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Tris(2,6-dibenzoyl-4-methyl-phenolato-κ(2) O (1),O (2))cobalt(III).

ABSTRACT: In the title compound, [Co(C21H15O3)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methyl-phenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)°. The crystal packing is stabilized by weak inter-molecular C-H⋯O inter-actions. Mol-ecules are further linked by two π-π [centroid-centroid distances = 3.8612 (14) and 3.9479 (14) Å] and four C-H⋯π inter-actions, forming a three-dimensional network.

SUBMITTER: Gupta AK 

PROVIDER: S-EPMC3998268 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Tris(2,6-dibenzoyl-4-methyl-phenolato-κ(2) O (1),O (2))cobalt(III).

Gupta Abhishek K AK   Srivastava Sanjay S   Butcher Ray J RJ  

Acta crystallographica. Section E, Structure reports online 20140129 Pt 2

In the title compound, [Co(C21H15O3)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methyl-phenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)°. The crystal packing is stabilized by weak inter-molecular C-H⋯O inter-actions. M  ...[more]

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