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A second polymorph of (Z)-3-amino-4-(2-phenyl-hydrazinyl-idene)-1H-pyrazol-5(4H)-one.

ABSTRACT: The mol-ecule of the title compound, C9H9N5O, is approximately planar (the r.m.s. deviation of all non-H atoms is 0.08?Å). The amine substituent is pyramidal at the N atom. An intra-molecular N-Hhydrazine?O=C hydrogen bond is present. In the crystal, mol-ecules are connected via N-H?N and N-H?O hydrogen bonds, forming infinite layers parallel to (010). This polymorph is triclinic, space group P-1, whereas the previously reported form was monoclinic, space group P21/c [Elgemeie et al. (2013 ?). Acta Cryst. E69, o187], with stepped layers and a significantly lower density.

SUBMITTER: Elgazwy AS 

PROVIDER: S-EPMC3998306 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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A second polymorph of (Z)-3-amino-4-(2-phenyl-hydrazinyl-idene)-1H-pyrazol-5(4H)-one.

Elgazwy Abdel-Sattar S Hamad AS   Jones Peter G PG  

Acta crystallographica. Section E, Structure reports online 20140115 Pt 2

The mol-ecule of the title compound, C9H9N5O, is approximately planar (the r.m.s. deviation of all non-H atoms is 0.08 Å). The amine substituent is pyramidal at the N atom. An intra-molecular N-Hhydrazine⋯O=C hydrogen bond is present. In the crystal, mol-ecules are connected via N-H⋯N and N-H⋯O hydrogen bonds, forming infinite layers parallel to (010). This polymorph is triclinic, space group P-1, whereas the previously reported form was monoclinic, space group P21/c [Elgemeie et al. (2013 ▶). A  ...[more]

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