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9-[4-(Azido-meth-yl)phen-yl]-9H-carbazole-3-carbo-nitrile.

ABSTRACT: In the title compound C20H13N5, the dihedral angle between the carbazole ring system (r.m.s. deviation = 0.027?Å) and the pendant benzene ring is 55.08?(6)°. One of the azide N atoms is disordered over two positions in a 0.65?(2):0.35?(2) ratio. In the crystal, aromatic ?-? stacking is observed [minimum centroid-centroid separation = 3.6499?(13)?Å] as well as inversion-dimers connected by pairs of weak C-H?? inter-actions.

SUBMITTER: Ramathilagam C

PROVIDER: S-EPMC3998346 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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9-[4-(Azido-meth-yl)phen-yl]-9H-carbazole-3-carbo-nitrile.

Ramathilagam C C Umarani P R PR Venkatesan N N Rajakumar P P Gunasekaran B B Manivannan V V

Acta crystallographica. Section E, Structure reports online 20140125 Pt 2

In the title compound C20H13N5, the dihedral angle between the carbazole ring system (r.m.s. deviation = 0.027 Å) and the pendant benzene ring is 55.08 (6)°. One of the azide N atoms is disordered over two positions in a 0.65 (2):0.35 (2) ratio. In the crystal, aromatic π-π stacking is observed [minimum centroid-centroid separation = 3.6499 (13) Å] as well as inversion-dimers connected by pairs of weak C-H⋯π inter-actions. ...[more]

PMID: 24764907

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