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Ethyl 4,9-dimethyl-9H-carbazole-3-carboxyl-ate.

ABSTRACT: In the title compound, C17H17NO2, the carbazole skeleton includes an eth-oxy-carbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065?(2)?Å], and the ethyl ester group is inclined to its mean plane by 15.48?(2)°. In the crystal, there are ?-? stacking inter-actions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent mol-ecules [centroid-centroid distances = 3.9473?(8) and 3.7758?(8)?Å, respectively]. Weak C-H?? inter-actions are also present.

SUBMITTER: Oncuoglu S

PROVIDER: S-EPMC3998387 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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Ethyl 4,9-dimethyl-9H-carbazole-3-carboxyl-ate.

Oncüoğlu Serkan S Dilek Nefise N Caylak Delibaş Nagihan N Ergün Yavuz Y Hökelek Tuncer T

Acta crystallographica. Section E, Structure reports online 20140205 Pt 3

In the title compound, C17H17NO2, the carbazole skeleton includes an eth-oxy-carbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) Å], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π-π stacking inter-actions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent mol-ecules [centroid-centroid distances = 3.9473 (8) and 3.7758 (8) Å, respectively]. Weak C-H ...[more]

PMID: 24764961

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