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3-Anilino-5,5-di-methyl-cyclo-hex-2-enone.

ABSTRACT: In the title mol-ecule, C14H17NO, the 5,5-di-methyl-cyclo-hex-2-enone moiety is attached to an aniline group, the dihedral angle subtended [54.43?(3)°] indicating a significant twist. The hexaneone ring has a half-chair conformation with the C atom bearing two methyl groups lying 0.6384?(8)?Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0107?Å). The crystal packing can be described as alternating layers parallel to (-101), which are consolidated by N-H?O hydrogen bonds and C-H?? inter-actions.

SUBMITTER: Boulebd H 

PROVIDER: S-EPMC3998468 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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3-Anilino-5,5-di-methyl-cyclo-hex-2-enone.

Boulebd Houssem H   Bouraiou Abdelmalek A   Bouacida Sofiane S   Merazig Hocine H   Belfaitah Ali A  

Acta crystallographica. Section E, Structure reports online 20140205 Pt 3

In the title mol-ecule, C14H17NO, the 5,5-di-methyl-cyclo-hex-2-enone moiety is attached to an aniline group, the dihedral angle subtended [54.43 (3)°] indicating a significant twist. The hexaneone ring has a half-chair conformation with the C atom bearing two methyl groups lying 0.6384 (8) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0107 Å). The crystal packing can be described as alternating layers parallel to (-101), which are consolidated by N-H⋯O hydrogen bonds and C  ...[more]

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