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Trans-Chlorido-(4-fluoro-benzene-thiol-ato-?S)bis-(tri-phenyl-phosphane-?P)palladium(II) methanol hemisolvate.

ABSTRACT: The title compound, [Pd(SC6H4F-p)Cl(PPh3)2]·0.5CH3OH, features a Pd(II) complex with two tri-phenyl-phosphane (PPh3) ligands arranged in a trans conformation, with one chloride and one 4-fluoro-benzene-thiol-ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd(II) ion. The methanol solvent mol-ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C-H?Cl hydrogen-bonding inter-actions between the complex mol-ecules generate chain frameworks parallel to [010].

SUBMITTER: Avila-Sorrosa A

PROVIDER: S-EPMC3998499 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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trans-Chlorido-(4-fluoro-benzene-thiol-ato-κS)bis-(tri-phenyl-phosphane-κP)palladium(II) methanol hemisolvate.

Avila-Sorrosa Alcives A Santacruz-Juárez Ericka E Reyes-Arellano Alicia A Reyes-Martínez Reyna R Morales-Morales David D

Acta crystallographica. Section E, Structure reports online 20140212 Pt 3

The title compound, [Pd(SC6H4F-p)Cl(PPh3)2]·0.5CH3OH, features a Pd(II) complex with two tri-phenyl-phosphane (PPh3) ligands arranged in a trans conformation, with one chloride and one 4-fluoro-benzene-thiol-ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd(II) ion. The methanol solvent mol-ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C-H⋯Cl hydrogen-bonding inter- ...[more]

PMID: 24764953

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