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N''-(4-Meth-oxy-phen-yl)-N,N,N'-trimethyl-N'-phenyl-guanidine.

ABSTRACT: In the title compound, C17H21N3O, the C-N bond lengths in the guanidine unit are 1.2889?(19), 1.3682?(19) and 1.408?(2)?Å, indicating double- and single-bond character. The N-C-N angles are 115.10?(13), 119.29?(15) and 125.61?(14)°, showing a deviation of the CN3 plane from an ideal trigonal-planar geometry. In the crystal, non-classical C-H?O hydrogen bonds between methyl H atoms and meth-oxy O atoms are present, generating centrosymmetric dimers running in the [101] direction.

SUBMITTER: Tiritiris I

PROVIDER: S-EPMC3998528 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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N''-(4-Meth-oxy-phen-yl)-N,N,N'-trimethyl-N'-phenyl-guanidine.

Tiritiris Ioannis I Frey Wolfgang W Kantlehner Willi W

Acta crystallographica. Section E, Structure reports online 20140322 Pt 4

In the title compound, C17H21N3O, the C-N bond lengths in the guanidine unit are 1.2889 (19), 1.3682 (19) and 1.408 (2) Å, indicating double- and single-bond character. The N-C-N angles are 115.10 (13), 119.29 (15) and 125.61 (14)°, showing a deviation of the CN3 plane from an ideal trigonal-planar geometry. In the crystal, non-classical C-H⋯O hydrogen bonds between methyl H atoms and meth-oxy O atoms are present, generating centrosymmetric dimers running in the [101] direction. ...[more]

PMID: 24826159

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