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2-((1E)-1-{2-[(2Z)-3,4-Diphenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)pyridin-1-ium bromide monohydrate.

ABSTRACT: In the title compound, C22H19N4S(+)·Br(-)·H2O, the dihedral angles between the phenyl groups and the mean plane of the thia-zolyl-idene ring are 34.69?(13) and 64.27?(13)°, respectively, while that between the thia-zolyl-idene and pyridinium rings is 14.73?(13)°. In the crystal, zigzag chains of alternating bromide ions and water mol-ecules associate through O-H?Br inter-actions run in channels approximately parallel to the b axis. These chains help form parallel chains of cations through N-H?O, C-H?N and C-H?Br hydrogen bonds.

SUBMITTER: Akkurt M

PROVIDER: S-EPMC3998596 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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2-((1E)-1-{2-[(2Z)-3,4-Diphenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)pyridin-1-ium bromide monohydrate.

Akkurt Mehmet M Mague Joel T JT Mohamed Shaaban K SK Hassan Alaa A AA Albayati Mustafa R MR

Acta crystallographica. Section E, Structure reports online 20140326 Pt 4

In the title compound, C22H19N4S(+)·Br(-)·H2O, the dihedral angles between the phenyl groups and the mean plane of the thia-zolyl-idene ring are 34.69 (13) and 64.27 (13)°, respectively, while that between the thia-zolyl-idene and pyridinium rings is 14.73 (13)°. In the crystal, zigzag chains of alternating bromide ions and water mol-ecules associate through O-H⋯Br inter-actions run in channels approximately parallel to the b axis. These chains help form parallel chains of cations through N-H⋯O, ...[more]

PMID: 24826173

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2-((1E)-1-{2-[(2Z)-4-(4-Bromo-phen-yl)-3-phenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)pyridin-1-ium bromide monohydrate.

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