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1:1 Co-crystal of 4,4'-(ethene-1,2-di-yl)dipyridin-1-ium sulfate and hexa-aqua-iron(II) sulfate monohydrate.

ABSTRACT: In the title hydrated double salt, 4,4'-(ethene-1,2-di-yl)dipyridin-1-ium hexa-aqua-iron(II) bis-(sulfate) monohydrate, (C12H12N2)[Fe(H2O)6](SO4)2·H2O, the Fe(II) cation is coordin-ated by six water mol-ecules in a slightly distorted octa-hedral geometry; the two pyridine rings of the 4,4'-(ethene-1,2-di-yl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84?(10)°. In the crystal, the cations, sulfate anions and water mol-ecules of crystallization are linked by O-H?O, N-H?O and weak C-H?O hydrogen bonds, forming a three-dimensional supra-molecular network.

SUBMITTER: Yang D

PROVIDER: S-EPMC4011237 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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1:1 Co-crystal of 4,4'-(ethene-1,2-di-yl)dipyridin-1-ium sulfate and hexa-aqua-iron(II) sulfate monohydrate.

Yang Dan D Yang Fei-Lin FL

Acta crystallographica. Section E, Structure reports online 20140405 Pt 5

In the title hydrated double salt, 4,4'-(ethene-1,2-di-yl)dipyridin-1-ium hexa-aqua-iron(II) bis-(sulfate) monohydrate, (C12H12N2)[Fe(H2O)6](SO4)2·H2O, the Fe(II) cation is coordin-ated by six water mol-ecules in a slightly distorted octa-hedral geometry; the two pyridine rings of the 4,4'-(ethene-1,2-di-yl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84 (10)°. In the crystal, the cations, sulfate anions and water mol-ecules of crystallization are linked by O-H⋯O, N ...[more]

PMID: 24860304

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