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1,4-Diazo-niabi-cyclo-[2.2.2]octane tetra-chlorido-cadmate(II) monohydrate.

ABSTRACT: The asymmetric unit of the title compound (C6H14N2)[CdCl4]·H2O contained one 1,4-di-aza-bicyclo-[2.2.2]octane dication, a tetrahedral CdCl4 (2-) anion and a lattice water mol-ecule. In the crystal, the solvate water mol-ecule inter-acts with the cationic and anionic species via N-H?O and O-H?Cl [O?Cl = 3.289?(7)?Å] hydrogen-bond inter-actions, respectively, leading to a layered supramolecular structure extending parallel to (011).

SUBMITTER: Ben Rhaiem T 

PROVIDER: S-EPMC4011291 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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1,4-Diazo-niabi-cyclo-[2.2.2]octane tetra-chlorido-cadmate(II) monohydrate.

Ben Rhaiem Tarek T   Boughzala Habib H  

Acta crystallographica. Section E, Structure reports online 20140412 Pt 5

The asymmetric unit of the title compound (C6H14N2)[CdCl4]·H2O contained one 1,4-di-aza-bicyclo-[2.2.2]octane dication, a tetrahedral CdCl4 (2-) anion and a lattice water mol-ecule. In the crystal, the solvate water mol-ecule inter-acts with the cationic and anionic species via N-H⋯O and O-H⋯Cl [O⋯Cl = 3.289 (7) Å] hydrogen-bond inter-actions, respectively, leading to a layered supramolecular structure extending parallel to (011). ...[more]

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