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An acetonitrile solvatomorph of di-chlorido-(1,10-phenanthroline-5,6-dione)platinum(II).

ABSTRACT: In the title complex, [PtCl2(C12H6N2O2)]·CH3CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N2Cl2 donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally displaced with respect to each other. This prevents any overlap of the phenanthroline rings and thus there is no possibility of any ?-? inter-actions between aromatic rings.

SUBMITTER: Hamala A

PROVIDER: S-EPMC4029211 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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An acetonitrile solvatomorph of di-chlorido-(1,10-phenanthroline-5,6-dione)platinum(II).

Hamala Amanda A Fritz Carissa C Rawji Gulnar G Lynch Vincent V

Acta crystallographica. Section E, Structure reports online 20131211 Pt 1

In the title complex, [PtCl2(C12H6N2O2)]·CH3CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N2Cl2 donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally displaced with respect to each other. This prevents any overlap of the phenanthroline rings and thus there is no possibility of any π-π inter-actions between aromatic rings. ...[more]

PMID: 24855465

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