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N-[(9H-Fluoren-9-yl-idene)(2-meth-oxy-phen-yl)meth-yl]-1,1,1-tri-methyl-silanamine.

ABSTRACT: The title mol-ecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-tri-methyl-silyfluorenyl lithium and 2-meth-oxy-benzo-nitrile. The fluorene ring system is substanti-ally planar, with an r.m.s. deviation of 0.0288?Å from the best-fit plane through its 13?C atoms. This plane forms a dihedral angle of 58.07?(7)° with the 2-meth-oxy-benzyl-amine ring plane. In the crystal, mol-ecules are linked by N-H?? and C-H?? inter-actions, which leads to the formation of two-dimensional network lying parallel to the bc plane.

SUBMITTER: Li ZY

PROVIDER: S-EPMC4029215 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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N-[(9H-Fluoren-9-yl-idene)(2-meth-oxy-phen-yl)meth-yl]-1,1,1-tri-methyl-silanamine.

Li Zhong-Yuan ZY Wang Peng P Chen Xia X

Acta crystallographica. Section E, Structure reports online 20131214 Pt 1

The title mol-ecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-tri-methyl-silyfluorenyl lithium and 2-meth-oxy-benzo-nitrile. The fluorene ring system is substanti-ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-meth-oxy-benzyl-amine ring plane. In the crystal, mol-ecules are linked by N-H⋯π and C-H⋯π inter-actions, which leads to the formation of two-dimensional netwo ...[more]

PMID: 24855469

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