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Zinc(II) Complexes with Dangling Functional Organic Groups.


ABSTRACT: Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional p-substituted benzene derivatives (a combination of carboxylate, oximate, amino, ?-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or ?-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From the reaction with p-aminobenzoic acid, the compound [Zn2(OOCCH3)(OOC-C6H4-NH2)3]? was crystallized. It is a three-dimensional coordination polymer with bridging aminobenzoate ligands.

SUBMITTER: Yang J 

PROVIDER: S-EPMC4038256 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Zinc(II) Complexes with Dangling Functional Organic Groups.

Yang Jingxia J   Puchberger Michael M   Qian Renzhe R   Maurer Christian C   Schubert Ulrich U  

European journal of inorganic chemistry 20120816 27


Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional <i>p</i>-substituted benzene derivatives (a combination of carboxylate, oximate, amino, β-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From t  ...[more]

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