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Bis(cyclo-hexyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).

ABSTRACT: The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H?Cl hydrogen bonds. Every cation is involved in three N-H?Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).

SUBMITTER: Sarr M

PROVIDER: S-EPMC4051057 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature

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Bis(cyclo-hexyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).

Sarr Modou M Merkens Carina C Diassé-Sarr Aminata A Diop Libasse L Englert Ulli U

Acta crystallographica. Section E, Structure reports online 20140517 Pt 6

The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H⋯Cl hydrogen bonds. Every cation is involved in three N-H⋯Cl bonds to the chloride ligands of three different anions, and each chlo ...[more]

PMID: 24940206

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