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Branched Au nanostructures enriched with a uniform facet: facile synthesis and catalytic performances.

ABSTRACT: Well-defined noble metal nanocrystals (NMNCs) of a unique morphology yet a uniform facet have attracted broad interests. In this regard, those with a highly branched architecture have gained particular attention. Most of the currently existing branched NMNCs, however, are enclosed by mixed facets. We now report that branched Au nanoarchitectures could be facilely fabricated by mixing an aqueous solution of KAuCl?, an aqueous dispersion of graphene oxide, and ethanol under ambient conditions. Interestingly, unilike the conventional branched NMNCs, our unique Au nanostructures are predominately enriched with a uniform facet of {111}. Compared to the spherical Au nanostructures exposed with mixed facets, our branched nanospecies of a uniform facet display superior catalytic performances both for the catalytic reduction of 4-nitrophenol and the electrocatalytic oxidation of methanol. Our investigation represents the first example that Au nanostructures simultaneously featured with a highly branched architecture and a uniform crystal facet could be formulated. Our unique Au nanostructures provide a fundamental yet new scientific forum to disclose the correlation between the surface atomic arrangement and the catalytic performances of branched NMNCs.

SUBMITTER: Zhu M

PROVIDER: S-EPMC4052748 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature

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Branched Au nanostructures enriched with a uniform facet: facile synthesis and catalytic performances.

Zhu Mingshan M Lei Bin B Ren Fangfang F Chen Penglei P Shen Yunfan Y Guan Bo B Du Yukou Y Li Tiesheng T Liu Minghua M

Scientific reports 20140611

Well-defined noble metal nanocrystals (NMNCs) of a unique morphology yet a uniform facet have attracted broad interests. In this regard, those with a highly branched architecture have gained particular attention. Most of the currently existing branched NMNCs, however, are enclosed by mixed facets. We now report that branched Au nanoarchitectures could be facilely fabricated by mixing an aqueous solution of KAuCl₄, an aqueous dispersion of graphene oxide, and ethanol under ambient conditions. Int ...[more]

PMID: 24918973

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Project description:Spinel ferrites are versatile, low-cost, and abundant metal oxides with remarkable electronic and magnetic properties, which find several applications. Among them, they have been considered part of the next generation of electrochemical energy storage materials due to their variable oxidation states, low environmental toxicity, and possible synthesis through simple green chemical processing. However, most traditional procedures lead to the formation of poorly controlled materials (in terms of size, shape, composition, and/or crystalline structure). Thus, we report herein a cellulose nanofibers-mediated green procedure to prepare controlled highly porous nanocorals comprised of spinel Zn-ferrites. Then, they presented remarkable applications as electrodes in supercapacitors, which were thoroughly and critically discussed. The spinel Zn-ferrites nanocorals supercapacitor showed a much higher maximum specific capacitance (2031.81 F g-1 at a current density of 1 A g-1) than Fe2O3 and ZnO counterparts prepared by a similar approach (189.74 and 24.39 F g-1 at a current density of 1 A g-1). Its cyclic stability was also scrutinized via galvanostatic charging/discharging and electrochemical impedance spectroscopy, indicating excellent long-term stability. In addition, we manufactured an asymmetric supercapacitor device, which offered a high energy density value of 18.1 Wh kg-1 at a power density of 2609.2 W kg-1 (at 1 A g-1 in 2.0 mol L-1 KOH electrolyte). Based on our findings, we believe that higher performances observed for spinel Zn-ferrites nanocorals could be explained by their unique crystal structure and electronic configuration based on crystal field stabilization energy, which provides an electrostatic repulsion between the d electrons and the p orbitals of the surrounding oxygen anions, creating a level of energy that determines their final supercapacitance then evidenced, which is a very interesting property that could be explored for the production of clean energy storage devices.

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Branched Au nanostructures enriched with a uniform facet: facile synthesis and catalytic performances.

Publications

Branched Au nanostructures enriched with a uniform facet: facile synthesis and catalytic performances.

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