Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.
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ABSTRACT:
SUBMITTER: DeGuire SM
PROVIDER: S-EPMC4096701 | biostudies-literature | 2011 Oct
REPOSITORIES: biostudies-literature
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Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.
DeGuire Sean M SM Ma Shutao S Sulikowski Gary A GA
Angewandte Chemie (International ed. in English) 20110907 42
By design: a carbanion-mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide. ...[more]
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