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Plasmon Mapping in Au@Ag Nanocube Assemblies.

ABSTRACT: Surface plasmon modes in metallic nanostructures largely determine their optoelectronic properties. Such plasmon modes can be manipulated by changing the morphology of the nanoparticles or by bringing plasmonic nanoparticle building blocks close to each other within organized assemblies. We report the EELS mapping of such plasmon modes in pure Ag nanocubes, Au@Ag core-shell nanocubes, and arrays of Au@Ag nanocubes. We show that these arrays enable the creation of interesting plasmonic structures starting from elementary building blocks. Special attention will be dedicated to the plasmon modes in a triangular array formed by three nanocubes. Because of hybridization, a combination of such nanotriangles is shown to provide an antenna effect, resulting in strong electrical field enhancement at the narrow gap between the nanotriangles.

SUBMITTER: Goris B

PROVIDER: S-EPMC4106270 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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Plasmon Mapping in Au@Ag Nanocube Assemblies.

Goris Bart B Guzzinati Giulio G Fernández-López Cristina C Pérez-Juste Jorge J Liz-Marzán Luis M LM Trügler Andreas A Hohenester Ulrich U Verbeeck Jo J Bals Sara S Van Tendeloo Gustaaf G

The journal of physical chemistry. C, Nanomaterials and interfaces 20140627 28

Surface plasmon modes in metallic nanostructures largely determine their optoelectronic properties. Such plasmon modes can be manipulated by changing the morphology of the nanoparticles or by bringing plasmonic nanoparticle building blocks close to each other within organized assemblies. We report the EELS mapping of such plasmon modes in pure Ag nanocubes, Au@Ag core-shell nanocubes, and arrays of Au@Ag nanocubes. We show that these arrays enable the creation of interesting plasmonic structures ...[more]

PMID: 25067991

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