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Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.

ABSTRACT: A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

SUBMITTER: Gavette JV 

PROVIDER: S-EPMC4112994 | biostudies-literature |

REPOSITORIES: biostudies-literature

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