Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.
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ABSTRACT: A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.
SUBMITTER: Gavette JV
PROVIDER: S-EPMC4112994 | biostudies-literature |
REPOSITORIES: biostudies-literature
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