A journey into the active center of nitrogenase.
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ABSTRACT:
SUBMITTER: Hu Y
PROVIDER: S-EPMC4119499 | biostudies-literature | 2014 Aug
REPOSITORIES: biostudies-literature
Publications
A journey into the active center of nitrogenase.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20140422 6
Nitrogenase catalyzes the reduction of N2 to NH3, a key step in the global nitrogen cycle. This article describes our journey toward the definition of a complete molecular structure of the active site of nitrogenase, with an emphasis on the discovery of the interstitial carbide and the radical SAM-dependent insertion of this atom into the active FeMo cofactor site of nitrogenase. ...[more]
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