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N (1)-[(1H-Imidazol-2-yl)methyl-idene]-N (4)-phenyl-benzene-1,4-di-amine.

ABSTRACT: The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenyl-enedi-amine rings of 30.66?(4)° and between the planes of the phenyl-enedi-amine and N-phenyl rings of 56.63?(7)°. In the crystal, mol-ecules are connected by N-H?N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C-H?? inter-actions between N-phenyl and imidazole rings and slipped ?-? stacking inter-actions between imidazole rings [centroid-centroid distance = 3.516?(4)?Å] giving an overall two-dimensional layered structure lying parallel to (010).

SUBMITTER: Faizi MS

PROVIDER: S-EPMC4120595 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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N (1)-[(1H-Imidazol-2-yl)methyl-idene]-N (4)-phenyl-benzene-1,4-di-amine.

Faizi Md Serajul Haque MS Mashrai Ashraf A Shahid M M Ahmad Musheer M

Acta crystallographica. Section E, Structure reports online 20140625 Pt 7

The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenyl-enedi-amine rings of 30.66 (4)° and between the planes of the phenyl-enedi-amine and N-phenyl rings of 56.63 (7)°. In the crystal, mol-ecules are connected by N-H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C-H⋯π inter-actions between N-phenyl and imidazole rings and slipped π-π stacking inter-actions between im ...[more]

PMID: 25161587

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