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(N-Phenyl-thio-urea-?S)bis-(tri-phenylphosphane-?P)silver(I) nitrate.

ABSTRACT: In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372?(1)?Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H?O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H?? inter-actions, generating a three-dimensional network.

SUBMITTER: Mekarat S

PROVIDER: S-EPMC4120613 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Mekarat Sofia S Pakawatchai Chaveng C Saithong Saowanit S

Acta crystallographica. Section E, Structure reports online 20140625 Pt 7

In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network. ...[more]

PMID: 25161537

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