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(?(6)-Benzene)-dichlorido-(chloro-dicyclo-hexyl-phosphane-?P)ruthenium(II) chloro-form monosolvate.

ABSTRACT: The title compound, [RuCl2(?(6)-C6H6)(C12H22ClP)]·CHCl3, was prepared by reaction of [RuCl2(?(6)-C6H6)]2 with chloro-dicyclo-hexyl-phosphane in CHCl3 at 323?K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru-P bond length of 2.3247?(4)?Å. Both cyclo-hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol-ecule and the chloro-form solvent mol-ecule are linked by a bifurcated C-H?(Cl,Cl) hydrogen bond. Intra-molecular C-H?Cl hydrogen bonds are also observed.

SUBMITTER: Gowrisankar S

PROVIDER: S-EPMC4120624 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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(η(6)-Benzene)-dichlorido-(chloro-dicyclo-hexyl-phosphane-κP)ruthenium(II) chloro-form monosolvate.

Gowrisankar Saravanan S Neumann Helfried H Spannenberg Anke A Beller Matthias M

Acta crystallographica. Section E, Structure reports online 20140611 Pt 7

The title compound, [RuCl2(η(6)-C6H6)(C12H22ClP)]·CHCl3, was prepared by reaction of [RuCl2(η(6)-C6H6)]2 with chloro-dicyclo-hexyl-phosphane in CHCl3 at 323 K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru-P bond length of 2.3247 (4) Å. Both cyclo-hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol-ecule and the chloro-f ...[more]

PMID: 25161521

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(?(6)-Benzene)-dichlorido(dicyclo-hexyl-phenyl-phosphane)ruthenium(II) benzene sesquisolvate.

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