Total synthesis of 1-oxomiltirone via Suzuki coupling
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ABSTRACT: Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1 and miltirone 4, a versatile intermediate 6 was found. The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees in selected abietane diterpenes when synthesized through high yield Suzuki reaction and subsequent cyclization, and total synthesis of 1-oxomiltirone (1) has been achieved. Electronic Supplementary Material
Supplementary material is available for this article at 10.1007/s13659-013-0034-7 and is accessible for authorized users.
SUBMITTER: Li C
PROVIDER: S-EPMC4131665 | biostudies-literature | 2013 Jun
REPOSITORIES: biostudies-literature
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