Copper-doped CdSe/ZnS quantum dots: controllable photoactivated copper(I) cation storage and release vectors for catalysis.
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ABSTRACT: The first photoactivated doped quantum dot vector for metal-ion release has been developed. A facile method for doping copper(I) cations within ZnS quantum dot shells was achieved through the use of metal-dithiocarbamates, with Cu(+) ions elucidated by X-ray photoelectron spectroscopy. Photoexcitation of the quantum dots has been shown to release Cu(+) ions, which was employed as an effective catalyst for the Huisgen [3+2] cycloaddition reaction. The relationship between the extent of doping, catalytic activity, and the fluorescence quenching was also explored.
SUBMITTER: Bear JC
PROVIDER: S-EPMC4138996 | biostudies-literature |
REPOSITORIES: biostudies-literature
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