Unknown

Dataset Information

0

3,10,14,21-Tetra-kis(4-meth-oxy-phen-yl)penta-cyclo-[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro-form monosolvate.

ABSTRACT: The asymmetric unit of the title compound, C49H36O6·CHCl3, contains half an organic mol-ecule, the complete mol-ecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloro-form mol-ecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155]; the unit-cell characteristics take into account the presence of CHCl3. The dihedral angles between the planes of the naphthalene ring system and the meth-oxy-benzene rings are 71.05?(7) (syn to the central C=O group) and 57.27?(6)° (anti to the central C=O group). In the crystal, mol-ecules are linked by C-H?O inter-actions, generating C(12) chains running parallel to the b axis.

SUBMITTER: Gopinath S 

PROVIDER: S-EPMC4158498 | biostudies-literature | 2014 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

3,10,14,21-Tetra-kis(4-meth-oxy-phen-yl)penta-cyclo-[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro-form monosolvate.

Gopinath S S   Narayanan P P   Sethusankar K K   Nandakumar Meganathan M   Mohanakrishnan Arasambattu K AK  

Acta crystallographica. Section E, Structure reports online 20140723 Pt 8

The asymmetric unit of the title compound, C49H36O6·CHCl3, contains half an organic mol-ecule, the complete mol-ecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloro-form mol-ecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]; the unit-cell characteristics take into account the presence of CHCl3. The dihedral angles between the  ...[more]

Similar Datasets

Unknown 3,22-Dioxa-11,14-di-aza-penta-cyclo-[12.8.0.0(2,11).0(5,10).0(15,20)]docosa-5(10),6,8,15(20),16,18-hexa-ene-4,21-dione.
| S-EPMC3790403 | biostudies-literature
Unknown meso-(1S*,21R*)-25-Methyl-8,11,14-trioxa-22,24,25-triaza-tetra-cyclo-[19.3.1.0(2,7).0(15,20)]penta-cosa-2,4,6,15(20),16,18-hexa-ene-23-thione chloro-form monosolvate.
| S-EPMC3470208 | biostudies-literature
Unknown 24-Acetyl-8,11,14-trioxa-24,27-diaza-penta-cyclo-[19.5.1.1(22,26).0(2,7).0(15,20)]octa-cosa-2,4,6,15(20),16,18-hexaen-28-one.
| S-EPMC3393972 | biostudies-literature
Unknown Crystal structure of (1RS,21SR,22RS,24SR)-28-oxo-24-propyl-8,11,14-trioxa-24,27-di-aza-penta-cyclo[19.5.1.1(22,26).0(2,7).0(15,20)]octa-cosa-2,4,6,15(20),16,18-hexa-ene acetic acid monosolvate.
| S-EPMC4908554 | biostudies-literature
Unknown Dimethyl 2-[24-acetyl-28-oxo-8,11,14-trioxa-24,27-diaza-penta-cyclo-[19.5.1.1(22,26).0(2,7).0(15,20)]octa-cosa-2,4,6,15(20),16,18-hexaen-27-yl]but-2-enedioate.
| S-EPMC3414347 | biostudies-literature
Unknown Penta-ammonium hepta-sodium bis-[penta-kis(?(2)-oxido)deca-oxido-bis-(?(5)-phosphato)penta-molybdenum(VI)] henicosa-hydrate.
| S-EPMC2983582 | biostudies-literature
Unknown Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-aza-tetra-cyclo-[19.3.1.0(2,7).0(15,20)]penta-cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate.
| S-EPMC3344514 | biostudies-literature
Unknown Crystal structure of 22,24,25-trimethyl-8,11,14-trioxa-25-aza-tetra-cyclo-[19.3.1.0<sup>2,7</sup>.0<sup>15,20</sup>]penta-cosa-2,4,6,15(20),16,18-hexaen-23-one.
| S-EPMC5290547 | biostudies-literature
Unknown Ethyl 4-(2-eth-oxy-2-oxoeth-yl)-3-oxo-4,13-di-aza-penta-cyclo-[11.8.0.0(2,11).0(5,10).0(14,19)]henicosa-1,5(10),6,8,11,14(19),15,17,20-nona-ene-12-carboxyl-ate.
| S-EPMC3770398 | biostudies-literature
Unknown Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza-tetra-cyclo-[19.3.1.0(2,7).0(15,20)]penta-cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate.
| S-EPMC3379201 | biostudies-other