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Crystal structure of ethyl 2-chloro-6-methyl-quinoline-3-carboxyl-ate.

ABSTRACT: In the title compound, C13H12ClNO2, the dihedral angle between the planes of the quinoline ring system (r.m.s. deviation = 0.029?Å) and the ester group is 54.97?(6)°. The C-O-C-Cm (m = meth-yl) torsion angle is -140.62?(16)°. In the crystal, mol-ecules inter-act via aromatic ?-? stacking [shortest centroid-centroid separation = 3.6774?(9)?Å] generating (010) sheets.

SUBMITTER: Hayour H

PROVIDER: S-EPMC4186161 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of ethyl 2-chloro-6-methyl-quinoline-3-carboxyl-ate.

Hayour Hasna H Bouraiou Abdelmalek A Bouacida Sofiane S Benzerka Saida S Belfaitah Ali A

Acta crystallographica. Section E, Structure reports online 20140801 Pt 9

In the title compound, C13H12ClNO2, the dihedral angle between the planes of the quinoline ring system (r.m.s. deviation = 0.029 Å) and the ester group is 54.97 (6)°. The C-O-C-Cm (m = meth-yl) torsion angle is -140.62 (16)°. In the crystal, mol-ecules inter-act via aromatic π-π stacking [shortest centroid-centroid separation = 3.6774 (9) Å] generating (010) sheets. ...[more]

PMID: 25309267

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