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Crystal structure of 4-chloro-2-iodo-aniline.

ABSTRACT: In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N-H?N hydrogen bonding, creating [100] chains. A Cl?I contact is observed [3.7850?(16)?Å]. The parallel planes of neigbouring mol-ecules reveal highly offset ?-stacking characterized by a centroid-centroid distance of 4.154?(1), a centroid-to-plane distance of 3.553?(3) and ring-offset slippage of 2.151?(6)?Å.

SUBMITTER: Quinn TR

PROVIDER: S-EPMC4186172 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of 4-chloro-2-iodo-aniline.

Quinn Taylor R TR Tanski Joseph M JM

Acta crystallographica. Section E, Structure reports online 20140801 Pt 9

In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N-H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol-ecules reveal highly offset π-stacking characterized by a centroid-centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å. ...[more]

PMID: 25309269

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