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Crystal structure of poly[{?-N,N'-bis[(pyridin-4-yl)meth-yl]oxalamide}-?-oxalato-cobalt(II)].

ABSTRACT: In the polymeric title compound, [Co(C2O4)(C14H14N4O2)] n , the Co(II) atom is six-coordinated by two N atoms from symmetry-related bis-[(pyridin-4-yl)meth-yl]oxalamide (BPMO) ligands and four O atoms from two centrosymmetric oxalate anions in a distorted octa-hedral coordination geometry. The Co(II) atoms are linked by the oxalate anions into a chain running parallel to [100]. The chains are linked by the BPMO ligands into a three-dimensional architecture. In addition, N-H?O hydrogen bonds stabilize the crystal packing.

SUBMITTER: Zou H

PROVIDER: S-EPMC4186178 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of poly[{μ-N,N'-bis[(pyridin-4-yl)meth-yl]oxalamide}-μ-oxalato-cobalt(II)].

Zou Hengye H Qi Yanjuan Y

Acta crystallographica. Section E, Structure reports online 20140801 Pt 9

In the polymeric title compound, [Co(C2O4)(C14H14N4O2)] n , the Co(II) atom is six-coordinated by two N atoms from symmetry-related bis-[(pyridin-4-yl)meth-yl]oxalamide (BPMO) ligands and four O atoms from two centrosymmetric oxalate anions in a distorted octa-hedral coordination geometry. The Co(II) atoms are linked by the oxalate anions into a chain running parallel to [100]. The chains are linked by the BPMO ligands into a three-dimensional architecture. In addition, N-H⋯O hydrogen bonds stab ...[more]

PMID: 25309173

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