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Crystal structure of 4-(prop-2-yn-yloxy)-2,2,6,6-tetra-methyl-piperidin-1-ox-yl.


ABSTRACT: The title compound, C12H20NO2, was synthesized from 4-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-oxyl (hy-droxy-TEMPO) and propargyl bromide. The six-membered ring adopts a flattened chair conformation and carries a propyn-yloxy substituent in an equatorial orientation at the 4-position. The N-O bond length of the piperidin-1-oxyl unit is 1.289?(3)?Å. In the crystal, C-H?O hydrogen bonds combine with unusual C-H?? inter-actions involving the alkyne unit as acceptor to generate a three-dimensional network.

SUBMITTER: Goswami SK 

PROVIDER: S-EPMC4186184 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of 4-(prop-2-yn-yloxy)-2,2,6,6-tetra-methyl-piperidin-1-ox-yl.

Goswami Shailesh K SK   Hanton Lyall R LR   McAdam C John CJ   Moratti Stephen C SC   Simpson Jim J  

Acta crystallographica. Section E, Structure reports online 20140809 Pt 9


The title compound, C12H20NO2, was synthesized from 4-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-oxyl (hy-droxy-TEMPO) and propargyl bromide. The six-membered ring adopts a flattened chair conformation and carries a propyn-yloxy substituent in an equatorial orientation at the 4-position. The N-O bond length of the piperidin-1-oxyl unit is 1.289 (3) Å. In the crystal, C-H⋯O hydrogen bonds combine with unusual C-H⋯π inter-actions involving the alkyne unit as acceptor to generate a three-dimensional  ...[more]

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