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Cycloadditions of cyclohexynes and cyclopentyne.


ABSTRACT: We report the strategic use of cyclohexyne and the more elusive intermediate, cyclopentyne, as a tool for the synthesis of new heterocyclic compounds. Experimental and computational studies of a 3-substituted cyclohexyne are also described. The observed regioselectivities are explained by the distortion/interaction model.

SUBMITTER: Medina JM 

PROVIDER: S-EPMC4207212 | biostudies-literature |

REPOSITORIES: biostudies-literature

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