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Silyl phosphorus and nitrogen donor chelates for homogeneous ortho borylation catalysis.

ABSTRACT: Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.

SUBMITTER: Ghaffari B

PROVIDER: S-EPMC4210111 | biostudies-literature | 2014 Oct

REPOSITORIES: biostudies-literature

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Silyl phosphorus and nitrogen donor chelates for homogeneous ortho borylation catalysis.

Ghaffari Behnaz B Preshlock Sean M SM Plattner Donald L DL Staples Richard J RJ Maligres Peter E PE Krska Shane W SW Maleczka Robert E RE Smith Milton R MR

Journal of the American Chemical Society 20141001 41

Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design. ...[more]

PMID: 25141136

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