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Silyl phosphorus and nitrogen donor chelates for homogeneous ortho borylation catalysis.


ABSTRACT: Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.

SUBMITTER: Ghaffari B 

PROVIDER: S-EPMC4210111 | biostudies-literature | 2014 Oct

REPOSITORIES: biostudies-literature

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Silyl phosphorus and nitrogen donor chelates for homogeneous ortho borylation catalysis.

Ghaffari Behnaz B   Preshlock Sean M SM   Plattner Donald L DL   Staples Richard J RJ   Maligres Peter E PE   Krska Shane W SW   Maleczka Robert E RE   Smith Milton R MR  

Journal of the American Chemical Society 20141001 41


Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design. ...[more]

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