Ontology highlight
ABSTRACT:
SUBMITTER: Carnegie RS
PROVIDER: S-EPMC4214138 | biostudies-literature | 2014 Oct
REPOSITORIES: biostudies-literature
Carnegie Ryan S RS Gibb Corinne L D CL Gibb Bruce C BC
Angewandte Chemie (International ed. in English) 20140905 43
The (1)H NMR spectroscopic analysis of the binding of the ClO4(-) anion to the hydrophobic, concave binding site of a deep-cavity cavitand is presented. The strength of association between the host and the ClO4(-) anion is controlled by both the nature and concentration of co-salts in a manner that follows the Hofmeister series. A model that partitions this trend into the competitive binding of the co-salt anion to the hydrophobic pocket of the host and counterion binding to its external carboxy ...[more]