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Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry.


ABSTRACT: A versatile strategy to prepare fac-[M(I)(CO)3](+) and cis-[M(I)(CO)2](+) (M = Re, (99m)Tc) complexes was developed using Huisgen click chemistry and monodentate phosphine ligands to readily incorporate biomolecules and tailor the chemical properties.

SUBMITTER: Hayes TR 

PROVIDER: S-EPMC4215957 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry.

Hayes Thomas R TR   Kasten Benjamin B BB   Barnes Charles L CL   Benny Paul D PD  

Dalton transactions (Cambridge, England : 2003) 20140407 19


A versatile strategy to prepare fac-[M(I)(CO)3](+) and cis-[M(I)(CO)2](+) (M = Re, (99m)Tc) complexes was developed using Huisgen click chemistry and monodentate phosphine ligands to readily incorporate biomolecules and tailor the chemical properties. ...[more]

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