Ontology highlight
ABSTRACT:
SUBMITTER: O'Sullivan S
PROVIDER: S-EPMC4227565 | biostudies-literature | 2014 Jan
REPOSITORIES: biostudies-literature
O'Sullivan Steven S Doni Eswararao E Tuttle Tell T Murphy John A JA
Angewandte Chemie (International ed. in English) 20131206 2
A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a) ArCNR and b) ArNC bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and to C in (b), by lowering LUMO energies and by stabilizing the products of fragmentation. ...[more]