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Crystal structure of the cage derivative penta-cyclo-[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl-ene di-thio-ketal.


ABSTRACT: The title penta-cyclo-undecane cage derivative, C13H14OS2, was identified during a thio-ketalization reaction. The reaction selectively gave the title compound and the product corresponding to bis-ketal was not formed. The title compound exhibits unusual Csp (3)-Csp (3) single bond lengths ranging from 1.495?(3) to 1.581?(2) and strained bond angles as small as 89.29?(12) and as large as 115.11?(11)°.

SUBMITTER: Kotha S 

PROVIDER: S-EPMC4257192 | biostudies-literature | 2014 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of the cage derivative penta-cyclo-[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl-ene di-thio-ketal.

Kotha Sambasivarao S   Sreenivasachary Nampalli N   Deodhar Deepak D   Shaikh Mobin M  

Acta crystallographica. Section E, Structure reports online 20140924 Pt 10


The title penta-cyclo-undecane cage derivative, C13H14OS2, was identified during a thio-ketalization reaction. The reaction selectively gave the title compound and the product corresponding to bis-ketal was not formed. The title compound exhibits unusual Csp (3)-Csp (3) single bond lengths ranging from 1.495 (3) to 1.581 (2) and strained bond angles as small as 89.29 (12) and as large as 115.11 (11)°. ...[more]

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