Ontology highlight
ABSTRACT:
SUBMITTER: Berger M
PROVIDER: S-EPMC4257239 | biostudies-literature | 2014 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20141024 Pt 11
The title solvated salt, C29H41N2 (+)·Br(-)·2CH2Cl2 was obtained from the reaction of the Arduengo-type carbene 1,3-bis-(2,6-diiso-propyl-phen-yl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si2Br6 in di-chloro-methane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8 (6)°; the dihedral angle between the benzene rings is 40.7 (2)°. The anion also lies on the mirror plane and both di-chlo ...[more]