Crystal structure of (4-chloro-phen-yl)[2-(10-hy-droxy-phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone.

ABSTRACT: In the title compound, C37H21ClO3, the dihedral angle between the two phenanthrene moieties is 57.79?(5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14?(8)°] and the furan unit makes dihedral angles of 70.27?(11) and 57.58?(8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring mol-ecules are connected via two inter-molecular hydrogen-bonding inter-actions (O-H?O and C-H?O) towards the carbonyl O atom with donor-acceptor distances of 2.824?(2) and 3.277?(3)?Å, creating an inversion dimer. A non-classical C-H?Cl inter-action [3.564?(2)?Å] and three C-H?? inter-actions, with C?? distances of 3.709?(3), 3.745?(2) and 3.628?(3)?Å, connect the mol-ecules, forming a three-dimensional supra-molecular architecture in the solid state.

SUBMITTER: Sajitha LU 

PROVIDER: S-EPMC4257253 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature