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Crystal structure of dimethyl 3,3'-[(3-nitro-phen-yl)methyl-ene]bis-(1H-indole-2-carboxyl-ate) ethanol monosolvate.

ABSTRACT: In the title compound, C27H21N3O6·C2H5OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3?(5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9?(5) and 73.4?(3)°. In the crystal, mol-ecules are linked by N-H?O and O-H?O hydrogen bonds and weak C-H?? inter-actions into a three-dimensional supra-molecular architecture. A void of 33.0?(7)?Å(3) is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O-H?O hydrogen bond, reinforcing the framework structure.

SUBMITTER: Sun HS

PROVIDER: S-EPMC4257280 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of dimethyl 3,3'-[(3-nitro-phen-yl)methyl-ene]bis-(1H-indole-2-carboxyl-ate) ethanol monosolvate.

Sun Hong-Shun HS Li Yu-Long YL Jiang Hong H Xu Ning N Xu Hong H

Acta crystallographica. Section E, Structure reports online 20141024 Pt 11

In the title compound, C27H21N3O6·C2H5OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds and weak C-H⋯π inter-actions into a three-dimensional supra-molecular architecture. A void of 33.0 (7) Å(3) is observed in the crystal structure. The solvent ethanol mole ...[more]

PMID: 25484748

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