Ontology highlight
ABSTRACT:
SUBMITTER: Merola JS
PROVIDER: S-EPMC4257346 | biostudies-literature | 2014 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20141018 Pt 11
The molecule of the title compound, [IrCl(C7H5NS)(C3H9P)3], is a distorted octa-hedral iridium complex with three PMe3 ligands arranged in a meridional geometry, a chloride ion cis to all three PMe3 groups and the phenyl iso-thio-cyanate ligand bonded in an η(2)-fashion through the C and S atoms. The C atom is trans to the chloride ion and the S atom is responsible for a significant deviation from an ideal octa-hedral geometry. The geometric parameters for the metal-complexing phenyl isothiocyan ...[more]