Unknown

Dataset Information

0

Crystal structure of bis-[1-(4-bromo-benz-yl)pyridinium] bis-(1,2-di-cyano-ethene-1,2-di-thiol-ato-?(2) S,S')nickelate(II).

ABSTRACT: The asymmetric unit of the title salt, (C12H11BrN)2[Ni(C4N2S2)2], consists of one 1-(4-bromo-benz-yl)pyridinium cation and one half of a complex [Ni(mnt)2](2-) (mnt(2-) is the maleo-nitrile-dithiol-ate dianion). The Ni(2+) ion is located on an inversion centre and is coordinated by four S atoms from two mnt(2-) ligands, exhibiting a square-planar coordination environment. In the cation, the planes of the pyridinium and benzene rings make a dihedral angle of 69.86?(19)°. The cations and anions are alternately arranged in layers parallel to (001) and are held together by non-classical C-H?N hydrogen bonds.

SUBMITTER: Zeng D 

PROVIDER: S-EPMC4257415 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of bis-[1-(4-bromo-benz-yl)pyridinium] bis-(1,2-di-cyano-ethene-1,2-di-thiol-ato-κ(2) S,S')nickelate(II).

Zeng Dong D   Yang Shui-Bin SB   Tian Zheng-Fang ZF  

Acta crystallographica. Section E, Structure reports online 20141112 Pt 12

The asymmetric unit of the title salt, (C12H11BrN)2[Ni(C4N2S2)2], consists of one 1-(4-bromo-benz-yl)pyridinium cation and one half of a complex [Ni(mnt)2](2-) (mnt(2-) is the maleo-nitrile-dithiol-ate dianion). The Ni(2+) ion is located on an inversion centre and is coordinated by four S atoms from two mnt(2-) ligands, exhibiting a square-planar coordination environment. In the cation, the planes of the pyridinium and benzene rings make a dihedral angle of 69.86 (19)°. The cations and anions ar  ...[more]

Similar Datasets

Unknown Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC3050285 | biostudies-literature
Unknown Bis(1-ethyl-4,4'-bipyridin-1-ium) bis-(1,2-di-cyano-ethene-1,2-di-thiol-ato-?(2) S,S')nickelate(II).
| S-EPMC3793674 | biostudies-literature
Unknown Bis[1-(4-cyano-benz-yl)pyrazinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC3152075 | biostudies-literature
Unknown Crystal structure of bis-[1-(naphthalen-1-ylmeth-yl)pyridinium] bis-(2,2-di-cyano-ethene-1,1-di-thiol-ato-?(2) S,S')nickelate(II).
| S-EPMC4158505 | biostudies-literature
Unknown 1-(4-Cyano-benz-yl)-3,5-dimethyl-pyridinium bis-(benzene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3051972 | biostudies-literature
Unknown 1-Butyl-pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3246985 | biostudies-literature
Unknown 1-(2-Fluoro-benzyl-ideneamino)pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC2977634 | biostudies-literature
Unknown Bis[1-(eth-oxy-carbonyl-meth-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato-?(2)S,S')nickelate(II).
| S-EPMC3435580 | biostudies-literature
Unknown 1-(4-Iodo-benz-yl)-3-methyl-pyridinium bis-(benzene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3247529 | biostudies-literature
Unknown 1,1'-(Ethane-1,2-di-yl)dipyridinium bis-(1,2-di-cyano-ethene-1,2-di-thiol-ato-?(2) S,S')cuprate(II).
| S-EPMC3684877 | biostudies-other