Unknown

Dataset Information

0

Crystal structure of bis-{2,4-di-tert-butyl-6-[(iso-propyl-imino)-meth-yl]phenolato-?(2) N,O}zinc di-chloro-methane mono-solvate.

ABSTRACT: In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl-aldehyde imine ligands, leading to a distorted tetra-hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69?(6)°. Intra-molecular non-classical C-H?O hydrogen-bonding inter-actions are observed. In the crystal, the complex mol-ecules stack into columns along the a axis. Di-chloro-methane solvent mol-ecules are situated in the voids of this arrangement.

SUBMITTER: Hao YZ 

PROVIDER: S-EPMC4257443 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of bis-{2,4-di-tert-butyl-6-[(iso-propyl-imino)-meth-yl]phenolato-κ(2) N,O}zinc di-chloro-methane mono-solvate.

Hao Yuan-Zeng YZ  

Acta crystallographica. Section E, Structure reports online 20141105 Pt 12

In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl-aldehyde imine ligands, leading to a distorted tetra-hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra-molecular non-classical C-H⋯O hydrogen-bonding inter-actions are observed. In the crystal, the complex mol-ecules stack into columns along the a axis. Di-chloro-methane solvent mol-ecules are situated in the  ...[more]

Similar Datasets

Unknown Bis{μ-2,4-di-tert-butyl-6-[3-(1H-imidazol-1-yl)propyl-imino-meth-yl]phenolato}bis-[acetatocopper(II)].
| S-EPMC2914935 | biostudies-literature
Unknown (2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxy-benzyl-ideneamino)cyclo-hexyl]imino-meth-yl}phenolato)dimethyl-aluminum(III).
| S-EPMC2967927 | biostudies-literature
Unknown (6S)-2,4-Di-tert-butyl-6-[(4S,5R)-3-iso-propyl-4-methyl-5-phenyloxazolidin-2-yl]phenol.
| S-EPMC2983885 | biostudies-other
Unknown Tris(2,4-di-tert-butyl-phen-yl) phosphate.
| S-EPMC3008051 | biostudies-literature
Unknown Bis[2,4-dibromo-6-(n-propyl-imino-methyl)phenolato-?N,O]cobalt(II).
| S-EPMC3008039 | biostudies-literature
Unknown 2,4-Di-tert-butyl-6-[(2,5-difluorophenyl)iminomethyl]phenol.
| S-EPMC2970961 | biostudies-literature
Unknown 4,5-Bis(2,4-di-tert-butyl-phen-oxy)phthalonitrile.
| S-EPMC3051978 | biostudies-literature
Unknown {4-Bromo-2-[3-(diethyl-ammonio)propyl-imino-meth-yl]phenolato}diiodidozinc(II) methanol solvate.
| S-EPMC2971364 | biostudies-literature
Unknown Bis{2,4-dichloro-6-[3-(dimethyl-amino)propyl-imino-meth-yl]phenolato}copper(II).
| S-EPMC2970479 | biostudies-literature
Unknown Di-tert-butyl 3,5-dimethyl-1H-pyrrole-2,4-dicarboxyl-ate.
| S-EPMC3393944 | biostudies-literature