Dataset Information

Charging-free electrochemical system for harvesting low-grade thermal energy.

ABSTRACT: Efficient and low-cost systems are needed to harvest the tremendous amount of energy stored in low-grade heat sources (<100 °C). Thermally regenerative electrochemical cycle (TREC) is an attractive approach which uses the temperature dependence of electrochemical cell voltage to construct a thermodynamic cycle for direct heat-to-electricity conversion. By varying temperature, an electrochemical cell is charged at a lower voltage than discharge, converting thermal energy to electricity. Most TREC systems still require external electricity for charging, which complicates system designs and limits their applications. Here, we demonstrate a charging-free TREC consisting of an inexpensive soluble Fe(CN)6(3-/4-) redox pair and solid Prussian blue particles as active materials for the two electrodes. In this system, the spontaneous directions of the full-cell reaction are opposite at low and high temperatures. Therefore, the two electrochemical processes at both low and high temperatures in a cycle are discharge. Heat-to-electricity conversion efficiency of 2.0% can be reached for the TREC operating between 20 and 60 °C. This charging-free TREC system may have potential application for harvesting low-grade heat from the environment, especially in remote areas.

SUBMITTER: Yang Y

PROVIDER: S-EPMC4260536 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Charging-free electrochemical system for harvesting low-grade thermal energy.

Yang Yuan Y Lee Seok Woo SW Ghasemi Hadi H Ghasemi Hadi H Loomis James J Li Xiaobo X Kraemer Daniel D Zheng Guangyuan G Cui Yi Y Chen Gang G

Proceedings of the National Academy of Sciences of the United States of America 20141117 48

Efficient and low-cost systems are needed to harvest the tremendous amount of energy stored in low-grade heat sources (<100 °C). Thermally regenerative electrochemical cycle (TREC) is an attractive approach which uses the temperature dependence of electrochemical cell voltage to construct a thermodynamic cycle for direct heat-to-electricity conversion. By varying temperature, an electrochemical cell is charged at a lower voltage than discharge, converting thermal energy to electricity. Most TREC ...[more]

PMID: 25404325

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Project description:This research work proposes a novel priority aware schedule based charging algorithm that uses wireless power transfer (WPT) technique in order to charge embedded sensor nodes (SNs) in a wireless body area network (WBAN). Implanted sensor nodes in WBANs require energy for both information extraction and data transmission to the remote controller unit. Thus, energy shortage of these SNs deteriorates due to the data transmission process of the patient health monitoring system. However, continuous operation by means of electromagnetic induction for energy harvesting, obtained from ambient sources, reduces the overall efficiency of the primary unit. With this paradigm in sight, an algorithm demonstrating the modeling of a priority-based mechanism is proposed in order to ensure proper sensor voltage level and to reduce the transmission losses. Medium access control (MAC) protocols are used for inductive powering from the primary unit to the secondary unit in a collision-free centralized scheduling scheme. Therefore, the proposed wireless charging algorithm for implanted SNs in WBAN is designed as per carrier sense multiple access with collision avoidance (CSMA/CA) technique. Because of this, the overall power consumption of SNs for certain operation periods, successful charging probabilities for multiple SNs, and instantaneous power requirements are considered as key performance measures of analysis. It is assumed that proper energy storage in both transmitters and receivers can handle channel interference and traffic contention. Simulation results verify that a significant reduction in power consumption for the proposed priority aware algorithm will maintain almost similar output. For this reason, saturating class-C as well as class-E driver circuits have been used to justify the performance in two different circuit topologies. Effects of priority with respect to the full charge period have also been observed for the multi-node system. Furthermore, from performance analysis, it has been demonstrated that the scheduling scheme causes both single MOSFET composed saturating class-C and Lchoke modeled class-E associated driver circuits to be considerably more loss efficient than corresponding existing ones.

Dataset Information

Charging-free electrochemical system for harvesting low-grade thermal energy.

Publications

Charging-free electrochemical system for harvesting low-grade thermal energy.

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