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Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction.

ABSTRACT: Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolcular [1,5]-hydride shift/isomerization reaction has been realized, using the inherent reducing power of 3-pyrrolines. A series of N-arylpyrrole containing amines are obtained in high yields.

SUBMITTER: Jiang CH 

PROVIDER: S-EPMC4273273 | biostudies-literature | 2014

REPOSITORIES: biostudies-literature

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Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction.

Jiang Chun-Huan CH   Lei Xiantao X   Zhen Le L   Du Hong-Jin HJ   Wen Xiaoan X   Xu Qing-Long QL   Sun Hongbin H  

Beilstein journal of organic chemistry 20141205

Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolcular [1,5]-hydride shift/isomerization reaction has been realized, using the inherent reducing power of 3-pyrrolines. A series of N-arylpyrrole containing amines are obtained in high yields. ...[more]

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