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Photoactive rolled-up TiO2 microtubes: fabrication, characterization and applications†Electronic supplementary information (ESI) available. See DOI: 10.1039/c4tc00796dClick here for additional data file.

ABSTRACT: Because of its unique properties, titania (TiO2) represents a promising candidate in a wide variety of research fields. In this paper, some of the properties and potential applications of titania within rolled-up nanotechnology are explored. It is shown how the structural and optical properties of rolled titania microtubes can be controlled by properly tuning the microfabrication parameters. The rolling up of titania films on different sacrificial layers and containing different shapes, achieving a control on the diameter of the fabricated titania microtubes, is presented. In order to obtain the more photoactive crystalline form of titania, one during-fabrication and two post-fabrication methods are demonstrated. Interesting applications in the fields of photocatalysis and photonics are suggested: the use of titania rolled-up microtubes as micromotors and optical microresonators is presented.

SUBMITTER: Giudicatti S

PROVIDER: S-EPMC4285103 | biostudies-literature | 2014 Aug

REPOSITORIES: biostudies-literature

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Photoactive rolled-up TiO<sub>2</sub> microtubes: fabrication, characterization and applications†Electronic supplementary information (ESI) available. See DOI: 10.1039/c4tc00796dClick here for additional data file.

Giudicatti Silvia S Marz Sonja M SM Soler Lluís L Madani Abbas A Jorgensen Matthew R MR Sanchez Samuel S Schmidt Oliver G OG

Journal of materials chemistry. C 20140620 29

Because of its unique properties, titania (TiO<sub>2</sub>) represents a promising candidate in a wide variety of research fields. In this paper, some of the properties and potential applications of titania within rolled-up nanotechnology are explored. It is shown how the structural and optical properties of rolled titania microtubes can be controlled by properly tuning the microfabrication parameters. The rolling up of titania films on different sacrificial layers and containing different shape ...[more]

PMID: 25580249

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Project description:Thiol-ene 'click' chemistries have been widely used in biomaterials applications, including drug delivery, tissue engineering, and controlled cell culture, owing to their rapid, cytocompatible, and often orthogonal reactivity. In particular, hydrogel-based biomaterials formed by photoinitiated thiol-ene reactions afford spatiotemporal control over the biochemical and biomechanical properties of the network for creating synthetic materials that mimic the extracellular matrix or enable controlled drug release. However, the use of charged peptides functionalized with cysteines, which can form disulfides prior to reaction, and vinyl monomers that require multistep syntheses and contain ester bonds, may lead to undesired inhomogeneity or degradation under cell culture conditions. Here, we designed a thiol-ene hydrogel formed by the reaction of allyloxycarbonyl-functionalized peptides and thiol-functionalized poly(ethylene glycol). Hydrogels were polymerized by free radical initiation under cytocompatible doses of long wavelength ultraviolet light in the presence of water-soluble photoinitiators (lithium acylphosphinate, LAP, and 2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methyl-1-propanone, Irgacure 2959). Mechanical properties of these hydrogels were controlled by varying the monomer concentration to mimic a range of soft tissue environments, and hydrogel stability in cell culture medium was observed over weeks. Patterns of biochemical cues were created within the hydrogels post-formation and confirmed through the incorporation of fluorescently-labeled peptides and Ellman's assay to detect free thiols. Human mesenchymal stem cells remained viable after encapsulation and subsequent photopatterning, demonstrating the utility of the monomers and hydrogels for three-dimensional cell culture. This facile approach enables the formation and characterization of hydrogels with well-defined, spatially-specific properties and expands the suite of monomers available for three-dimensional cell culture and other biological applications.

Dataset Information

Photoactive rolled-up TiO2 microtubes: fabrication, characterization and applications†Electronic supplementary information (ESI) available. See DOI: 10.1039/c4tc00796dClick here for additional data file.

Publications

Photoactive rolled-up TiO<sub>2</sub> microtubes: fabrication, characterization and applications†Electronic supplementary information (ESI) available. See DOI: 10.1039/c4tc00796dClick here for additional data file.

Similar Datasets

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