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Boron clusters as highly stable magnesium-battery electrolytes.


ABSTRACT: Boron clusters are proposed as a new concept for the design of magnesium-battery electrolytes that are magnesium-battery-compatible, highly stable, and noncorrosive. A novel carborane-based electrolyte incorporating an unprecedented magnesium-centered complex anion is reported and shown to perform well as a magnesium-battery electrolyte. This finding opens a new approach towards the design of electrolytes whose likelihood of meeting the challenging design targets for magnesium-battery electrolytes is very high.

SUBMITTER: Carter TJ 

PROVIDER: S-EPMC4298798 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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Boron clusters as highly stable magnesium-battery electrolytes.

Carter Tyler J TJ   Mohtadi Rana R   Arthur Timothy S TS   Mizuno Fuminori F   Zhang Ruigang R   Shirai Soichi S   Kampf Jeff W JW  

Angewandte Chemie (International ed. in English) 20140212 12


Boron clusters are proposed as a new concept for the design of magnesium-battery electrolytes that are magnesium-battery-compatible, highly stable, and noncorrosive. A novel carborane-based electrolyte incorporating an unprecedented magnesium-centered complex anion is reported and shown to perform well as a magnesium-battery electrolyte. This finding opens a new approach towards the design of electrolytes whose likelihood of meeting the challenging design targets for magnesium-battery electrolyt  ...[more]

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