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Articulated rods - a novel class of molecular rods based on oligospiroketals (OSK).


ABSTRACT: We developed a new type of molecular rods consisting of two (or more) rigid units linked by a flexible joint. Consequently we called these constructs articulated rods (ARs). The syntheses of ARs were carried out by a flexible and modular approach providing access to a number of compounds with various functionalizations in terminal positions. First applications were presented with pyrene, cinnamoyl and anthracenyl labelled ARs.

SUBMITTER: Wessig P 

PROVIDER: S-EPMC4311589 | biostudies-literature | 2015

REPOSITORIES: biostudies-literature

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Articulated rods - a novel class of molecular rods based on oligospiroketals (OSK).

Wessig Pablo P   Merkel Roswitha R   Müller Peter P  

Beilstein journal of organic chemistry 20150116


We developed a new type of molecular rods consisting of two (or more) rigid units linked by a flexible joint. Consequently we called these constructs articulated rods (ARs). The syntheses of ARs were carried out by a flexible and modular approach providing access to a number of compounds with various functionalizations in terminal positions. First applications were presented with pyrene, cinnamoyl and anthracenyl labelled ARs. ...[more]

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