Ontology highlight
ABSTRACT:
SUBMITTER: Chlubna-Eliasova P
PROVIDER: S-EPMC4320762 | biostudies-literature | 2014 Jul
REPOSITORIES: biostudies-literature
Chlubná-Eliášová Pavla P Tian Yuyang Y Pinar Ana B AB Kubů Martin M Čejka Jiří J Morris Russell E RE
Angewandte Chemie (International ed. in English) 20140513 27
Hydrolysis of germanosilicate zeolites with the IWW structure shows two different outcomes depending on the composition of the starting materials. Ge-rich IWW (Si/Ge=3.1) is disassembled into a layered material (IPC-5P), which can be reassembled into an almost pure silica IWW on treatment with diethoxydimethylsilane. Ge-poor IWW (Si/Ge=6.4) is not completely disassembled on hydrolysis, but retains some 3D connectivity. This structure can be reassembled into IWW by incorporation of Al to fill the ...[more]