Unknown

Dataset Information

0

Crystal structure of O-isopropyl [bis-(tri-methyl-sil-yl)amino](tert-butyl-amino)-phosphino-thio-ate.

ABSTRACT: [Bis(tri-methyl-sil-yl)amino](tert-butyl-imino)-thio-phospho-rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i) PrO-H bond across the P=N bond, resulting in the title compound, C13H35N2OPSSi2. In the mol-ecule, the P atom possesses a distorted tetra-hedral environment involving two N atoms from (Me3Si)2N- and (t) BuNH- groups, one O atom from an (i) PrO group and one S atom, therefore the mol-ecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. In the crystal, a pair of enanti-omers form a centrosymmetric dimer via a pair of N-H⋯S hydrogen bonds.

SUBMITTER: Kovalenko OO 

PROVIDER: S-EPMC4331855 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of O-isopropyl [bis-(tri-methyl-sil-yl)amino](tert-butyl-amino)-phosphino-thio-ate.

Kovalenko Oleksandr O OO   Kinzhybalo Vasyl V   Brusylovets Oleksii A OA   Lis Tadeusz T  

Acta crystallographica. Section E, Crystallographic communications 20150101 Pt 1

[Bis(tri-methyl-sil-yl)amino](tert-butyl-imino)-thio-phospho-rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i) PrO-H bond across the P=N bond, resulting in the title compound, C13H35N2OPSSi2. In the mol-ecule, the P atom possesses a distorted tetra-hedral environment involving two N atoms from (Me3Si)2N- and (t) BuNH- groups, one O atom from an (i) PrO group and one S atom, therefore the mol-ecule has a stereocenter on the P atom but crystal symmetry leads to a racemate. I  ...[more]

Similar Datasets

Unknown 1,1'-Bis(tert-butyl-dimethyl-sil-yl)ferrocene.
| S-EPMC3588248 | biostudies-literature
Unknown Bis-(3-tert-butyl-pyridine-κN)bis-(4-tert-butyl-pyridine-κN)bis(thio-cyanato-κN)cadmium.
| S-EPMC3515124 | biostudies-literature
Unknown {2,6-Bis[(di-tert-butyl-phosphino)-methyl]-phenyl}chloridonickel(II).
| S-EPMC2959246 | biostudies-literature
Unknown Trans-bis-(3-tert-butyl-pyridine-κN)bis-(4-tert-butyl-pyridine-κN)bis-(thio-cyanato-κN)manganese(II).
| S-EPMC3515098 | biostudies-literature
Unknown (3R,4S,5R)-Methyl 3,5-bis-[(tert-butyl-dimethyl-sil-yl)-oxy]-4-meth-oxy-cyclo-hex-1-ene-carboxyl-ate.
| S-EPMC3647833 | biostudies-literature
Unknown Crystal structure of (tert-butyl-dimethyl-sil-yl)tri-phenyl-germane, Ph3Ge-SiMe2(t-Bu).
| S-EPMC4719953 | biostudies-literature
Unknown A second polymorph of [1,2-bis-(di-tert-butyl-phosphino)ethane]dichlorido-platinum(II).
| S-EPMC2960814 | biostudies-other
Unknown tert-Butyl (2S)-2-{3-[(R)-bis-(tert-but-oxy-carbon-yl)amino]-2-oxopiperidin-1-yl}-3-methyl-butano-ate.
| S-EPMC3247449 | biostudies-literature
Unknown tert-Butyl 4-isopropyl-2-oxo-6-phenyl-3,4-dihydro-2H-pyran-3-carboxyl-ate.
| S-EPMC2979271 | biostudies-literature
Unknown tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl-ate.
| S-EPMC3011429 | biostudies-literature