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Crystal structure of (1S,2R,4S)-1-[(morpholin-4-yl)meth-yl]-4-(prop-1-en-2-yl)cyclo-hexane-1,2-diol.

ABSTRACT: The asymmetric unit of the title compound, C14H25NO3, contains two independent mol-ecules with similar geometry. The morpholine and cyclo-hexane rings of both mol-ecules adopt a chair conformation. Intra-molecular O-H⋯N hydrogen bonds are observed. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds into chains parallel to the [101] direction. The chains are further connected through C-H⋯O hydrogen bonds forming undulating layers parallel to the (-101) plane. The absolute configuration was assigned by reference to an unchanging chiral centre in the synthetic procedure.

SUBMITTER: Outouch R

PROVIDER: S-EPMC4331882 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of (1S,2R,4S)-1-[(morpholin-4-yl)meth-yl]-4-(prop-1-en-2-yl)cyclo-hexane-1,2-diol.

Outouch Rachid R Oubaassine Saadia S Ait Ali Mustapha M El Firdoussi Larbi L Spannenberg Anke A

Acta crystallographica. Section E, Crystallographic communications 20150101 Pt 1

The asymmetric unit of the title compound, C14H25NO3, contains two independent mol-ecules with similar geometry. The morpholine and cyclo-hexane rings of both mol-ecules adopt a chair conformation. Intra-molecular O-H⋯N hydrogen bonds are observed. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds into chains parallel to the [101] direction. The chains are further connected through C-H⋯O hydrogen bonds forming undulating layers parallel to the (-101) plane. The absolute configuration ...[more]

PMID: 25705457

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