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Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family.

ABSTRACT: We report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increase in hydrostatic pressure. The results confirm for the first time the Negative Linear Compressibility behaviour of this family of materials recently predicted from quantum chemical calculations.

SUBMITTER: Serra-Crespo P

PROVIDER: S-EPMC4338503 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family.

Serra-Crespo Pablo P Dikhtiarenko Alla A Stavitski Eli E Juan-Alcañiz Jana J Kapteijn Freek F Coudert François-Xavier FX Gascon Jorge J

CrystEngComm 20150101 2

We report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH<sub>2</sub>-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increase in hydrostatic pressure. The results confirm for the first time the Negative Linear Compressibility behaviour of this fa ...[more]

PMID: 25722647

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MIL-53 Metal-Organic Framework as a Flexible Cathode for Lithium-Oxygen Batteries.

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